Combine salt, sugar, and one can of peach nectar in a saucepan and heat on low, stirring until the salt and sugar have dissolved
Allow mixture to cool and stir in water and the rest of the nectar
Place pork chops in the brine, completely submerged, and refrigerate for 1 to 2 hours
Preheat the smoker to 225°F (107°C)
Drain the brine and pat the chops dry with a paper towel. Season all sides generously with the dry rub.
Once the smoker is preheated, place the chops on the rack and cook for 60 to 90 minutes until internal temperature reaches 145°F (63°C)
Remove chops from the smoker and place on a plate, tenting with aluminum foil to rest for 5 to 10 minutes
If preferred, sear each side of the chops for 1 to 2 minutes on a charcoal grill at high heat. Serve and enjoy immediately.